Sonoelectrochemical analysis of trace metals

Sonoelectrochemical analysis of trace metals.

Ultrasonically-enhanced mass transport was exploited to increase preconcentration efficiency in anodic stripping voltammetry. We developed a Nafion-coated mercury thin-film working electrode which is stable under ultrasonic irradiation, making it possible to achieve very low limits of detection for relatively short preconcentration times. This allows the investigation of a variety of biological...

Anodic stripping voltammetry of trace metals by batch injection analysis

The application of batch injection analysis to the determination of trace metals in samples of volume s 100 ~1 by square wave anodic stripping voltammetry has been investigated in detail, using a programmable electronic micropipette. The in situ formation of a mercury film on a glassy carbon electrode substrate, the influence of preconcentration time, injection rate and injected volume of analy...

Trace Metals Analysis in the Sediments of the Southern Caspian Sea

In this study, concentration of 17 elements, including As, Ba, Cd, Co, Cu, Hg, Mn, Ni, Pb, Zn, Ca,Fe, Mg, Na, P, S, Si, as well as methylmercury in 31 surface sediments were assessed. The sampling stations were Gulf of Golestan, Miankale Island, Babolsar, Nowshahr and Anzali, which represented the most important harbors in the Golestan, Mazandaran and Gilan provinces in the southern parts of th...

Trace Metals and Phosphorous Speciation

Trace metals and hemoglobin metabolism.

Hemoglobin is composed of two pairs of globin chains to which are attached four iron-containing metalloporphyrins. Factors regulating hemoglobin synthesis include the availability of iron and the presence of heme. Heme production occurs by enzymatic synthesis and includes a step mediated by aminolevulinic acid dehydrase, which is zinc-dependent and, thus, susceptible to the toxic effects of oth...